Adsorption and removal of herbicide paraquat from aqueous solutions via novel bimetal organic framework: Kinetics, equilibrium and statistical surface modeling

Abstract

This study examines the adsorption and removal of the herbicide paraquat in relation to a bimetal organic framework known as the Terbium/Palladium Metal-Organic Framework (Tb/Pd-MOF). Analysis of N2 adsorption/desorption isotherms, which were used to assess the properties of the Tb/Pd-MOF, revealed that the absorption of paraquat on Tb/Pd-MOF resulted in a reduction in pore volume, pore size, and surface area. Specifically, the pore volume decreased from 8.25 to 5.68 cm3/g, the pore size decreased from 11.34 nm to 8.92 nm, and the surface area decreased from 1456.61 to 1262.82 m2/g. The pore radius also decreased from 0.96 nm to 0.58 nm. Tb/Pd-MOF’s functional groups were identified through FT-IR, and the structure of the compound was confirmed using XPS. Various adsorption parameters including temperature, adsorbent dosage, pH, paraquat concentration, and contact time were studied. Density functional theory (DFT) was used to understand the electrical properties, reactivity, and morphology of paraquat. Results from the DFT analysis revealed that the electrophilic and nucleophilic attack sites aligned with the molecular orbitals (HOMO and LUMO) and MEP outcomes. The study found that Tb/Pd-MOF demonstrated a significant absorption capacity for paraquat, with adsorption data consistent with the Langmuir isotherm and pseudo-second-order kinetic models. The paraquat adsorption capability of Tb/Pd-MOF was determined to be 574.8 mg/g. Furthermore, chemisorption was identified as the primary form of adsorption, as indicated by the adsorption energy of 26.98 kJ·mol−1. The optimal conditions for achieving a high adsorption capacity were identified as pH 8 and 0.02 g of Tb/Pd-MOF. The temperature-dependent changes in the thermodynamic parameters ΔG°, ΔH°, and ΔS° indicated that the paraquat absorption onto Tb/Pd-MOF occurred spontaneously, was endothermic, and involved random processes. To optimize the absorption process, Response Surface Methodology and Box-Behnken design (RSM, BBD) were employed. These techniques enabled effective removal of paraquat from the Tb/Pd-MOF material. During chemisorption, the adsorbate and adsorbent form chemical bonds, while aromatic rings are involved in π-π bonding. Additionally, pore-filling occurs when the adsorbate fills the pores of the adsorbent, and electrostatic interactions result from the attraction or repulsion of charges between the adsorbate and adsorbent. As a means of eliminating paraquat from wastewater, Tb/Pd-MOF demonstrates significant potential due to its diverse absorption processes and high capacity for adsorption.