Abstract
Rates of butane adsorption on platinum black in sulfuric acid have been measured at 95°C using voltammetry in a flow‐through electrode system. Initial adsorption rates showed a strong dependence on potential in the range 100–300 mv vs. the reversible hydrogen electrode. This effect was shown to arise from blockage of butane adsorption sites by adsorbed hydrogen atoms. The data strongly indicate that butane adsorbs only on Type II (most anodic) H sites.
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