Abstract

The asymmetric unit of the title compound, 2C10H11N5O·C6H10O4, consists of a 2,4-diamino-6-(4-meth­oxy­phen­yl)-1,3,5-triazine mol­ecule and one-half mol­ecule of adipic acid which lies about an inversion center. The triazine ring makes a dihedral angle of 12.89 (4)° with the adjacent benzene ring. In the crystal, the components are linked by N—H⋯O and O—H⋯N hydrogen bonds, thus generating a centrosymmetric 2 + 1 unit of triazine and adipic acid mol­ecules with R 2 2(8) motifs. The triazine mol­ecules are connected to each other by N—H⋯N hydrogen bonds, forming an R 2 2(8) motif and a supra­molecular ribbon along the c axis. The 2 + 1 units and the supra­molecular ribbons are further inter­linked by weak N—H⋯O, C—H⋯O and C—H⋯π inter­actions, resulting in a three-dimensional network.

Highlights

  • The asymmetric unit of the title compound, 2C10H11N5OC6H10O4, consists of a 2,4-diamino-6-(4-methoxyphenyl)1,3,5-triazine molecule and one-half molecule of adipic acid which lies about an inversion center

  • The components are linked by N—H O and O—

  • For the stability of the temperature controller used in the data collection, see: Cosier & Glazer (1986)

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Summary

Structure Reports

Crystal data a School of Physics, Universiti Sains Malaysia, 11800 USM, Penang, Malaysia, b. R factor = 0.039; wR factor = 0.126; data-to-parameter ratio = 23.7. The asymmetric unit of the title compound, 2C10H11N5OC6H10O4, consists of a 2,4-diamino-6-(4-methoxyphenyl)1,3,5-triazine molecule and one-half molecule of adipic acid which lies about an inversion center. The triazine ring makes a dihedral angle of 12.89 (4) with the adjacent benzene ring. The components are linked by N—H O and O—. N—H N hydrogen bonds, forming an R22(8) motif and a supramolecular ribbon along the c axis. The 2 + 1 units and the supramolecular ribbons are further interlinked by weak N—. H O, C—H O and C—H interactions, resulting in a three-dimensional network

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