Abstract
In the monomeric title complex, [Co(C6H8O4)(C10H9N3)(H2O)2]·3H2O, the distorted octahedral CoN2O4 coordination environment comprises two N-atom donors from the bidentate dipyridyldiamine ligand, two O-atom donors from one of the carboxylate groups of the bidentate chelating adipate ligand and two water molecules. In addition, there are three solvent water molecules which are involved in both intra- and inter-unit O—H⋯O hydrogen-bonding interactions, which together with an amine–water N—H⋯O hydrogen bond produce a three-dimensional framework.
Highlights
In the monomeric title complex, [Co(C6H8O4)(C10H9N3)(H2O)2]3H2O, the distorted octahedral CoN2O4 coordination environment comprises two N-atom donors from the bidentate dipyridyldiamine ligand, two O-atom donors from one of the carboxylate groups of the bidentate chelating adipate ligand and two water molecules
There are three solvent water molecules which are involved in both intra- and inter-unit O—H O hydrogen-bonding interactions, which together with an amine–water N—H O hydrogen bond produce a three-dimensional framework
We are grateful for financial assistance from the DG–RSDT
Summary
Avignante,f and Hocine Merazigb a Département de Technologie, Faculté de Technologie, Université 20 Août 1955 de Skikda, 21000 Skikda, Algeria, bUnité de Recherche de Chimie de l’Environnement et Moléculaire Structurale (CHEMS), Université Constantine I, 25000 Constantine, Algeria, cLaboratoire de Chimie, Ingénierie Moléculaire et Nanostructures (LCIMN), Université Ferhat Abbas, Sétif I, 19000 Sétif, Algeria, dScience and Engineering. Queensland University of Technology, GPO Box 2434, Brisbane 4001, Australia, eClermont Université, Université Blaise Pascal, Institut de Chimie de Clermont-Ferrand, BP 10448, 63000 Clermont-Ferrand, France, and fCNRS UMR
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