Abstract
Equilibrium constants have been measured as a function of temperature for the charge transfer equilibria in mixtures of NO with aromatic compounds, and mixtures of aromatic compounds. The experimentally determined entropy changes are in good agreement with entropy changes calculated from statistical mechanical considerations provided an intermolecular component is included. The enthalpy changes for the charge transfer reactions correspond to the differences in the adiabatic ionization potentials of the compounds.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have