Adhesive and Impact-Peel Strength Improvement of Epoxy Resins Modified with Mono and Diamine Functionalized Elastomers

Abstract

Epoxy resins are widely applied in the automotive and electronic industries. However, pure epoxy resins are brittle and thus possess poor mechanical properties. Herein, we report a facile method for improving the impact-peel and adhesive strengths of epoxy resins via the incorporation of two different types of polyether amines (monoamine-based and diamine-based prepolymers). A comparative study was performed to investigate the potential advantages of incorporating a prepolymer into an epoxy resin matrix. It was discovered that the incorporation of a diamine prepolymer significantly improved the impact-peel strength of the epoxy resin system at low (-40°C) and room (23°C) temperatures. For 15 wt% adhesive loading, the diamine prepolymer-based epoxy system demonstrated a 130% (low temperature) and 32% (room temperature) higher impact-peel strength than the monoamine prepolymer-based epoxy system. Moreover, the 15 wt% diamine prepolymer-based epoxy system exhibited a significantly improved shear strength (~36 MPa) and T-peel strength (260 N/25 mm) owing to the effectively reduced crack propagation and cohesive interactions between the epoxy molecules. Our results suggest that the modification of epoxy resins with an appropriate amount of mono and diamine-functionalized elastomers provides a novel route for the development of highly efficient adhesive materials for various applications.