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Abstract
An eco-friendly poly (vinyl acetate) emulsion adhesive was synthesized without phthalate. Four types of eco-friendly plasticizers for use in these adhesives were selected to confirm their primary properties by injecting the eco-friendly plasticizer without any prior change to its processing or cost. The four types of eco-friendly plasticizers used were dibutyl phthalate DBP-based product, dialkyl ester, acetyl tributyl citrate, and pentandiol-di-isobutyrate. Their properties were determined by comparison with the existing (DBP)-based product. As a result, an emulsion adhesive was produced without addition of phthalate or need for additional additives, resulting in a significant decrease in cost. However, the low temperature characteristics of the eco-friendly plasticizers were slightly inferior to those of DBP. These adhesives containing eco-friendly plasticizer were studied and their characteristics for adhesion strength, water resistance, ability for low temperature film formation, excellent storage stability, and lack of volatile organic compounds productions (including phthalate) were confirmed.
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