Abstract

AbstractABA poly(styrene‐b‐isoprene) block copolymers with various molecular weights and composition were used as heat activated films in simple overlap glass joints. The influence of bonding temperature on their shear strength at break was investigated. On increase of temperature, the joint resistance for most of the copolymers passed through a maximum, which temperature was dependent on the molecular characteristics of the copolymers. The decrease in melt viscosity or chemical degradation could not explain the data. A morphological interpretation which fits well the present and previous observations is proposed and verified for one copolymer used in this work.

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