Abstract
Hyperfine coupling constants are reported for adducts of silyl, germyl and stannyl radicals with a series of substituted benzo [ b]thiophen-2,3-diones (Ia—Ip), benzo [ b] furan-2,3-dione (II), ninhydrin (III), and thieno [ 3,2- b] thiophen-2,3-dione (IV). The conformational and electronic properties of these radicals are compared with those of similar adducts formed by diaryl ketones.
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