Abstract
Abstract The base-adducts of nickel(II) complexes of S-methyl hydrazine carbodithioate Schiff bases with 2,2′-bipyridyl and 1,10-phenanthroline are prepared and isolated in benzene and acetonitrile, and analysed. Structures are suggested on the basis of IR and electronic spectra. Adduct formation with 2,2′-bipyridyl has been studied in a dichloro-ethane solution, spectrophotometrically. The results obtained suggest the formation of the cis -octahedral monoadduct.
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