Abstract
Nine new N-(thioalkyl) ehtylindoles and imidazoles were synthesized. Analysis of the PMR spectra of these compounds showed that, in the presence of radical activators, mercaptans are mainly added to N-vinylindole and to N-vinylimidazoles contrary to Markovikov rule. Under the influence of cathionic catalysts, Nvinylimidazole reacts in accordance with that rule. N-vinylindole polymerizes under these conditions, but Nvinylbenzoimidazole in general does not react.
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