Abstract

1. Addition of mercaptans of 3,5,5-trichloro-1,3-pentadiene proceeds with the formation of products of 1,2 and 1,4 addition. 2. Arguments are presented in favor of rearrangement of the CHCl2ĊHCCl=CHCH2SC4H9 radical to the ClĊHCHC1CCI=CHCH2SC4H9 radical during addition of butyl mercaptan to 3,5,5, -trichloro-1,3-pentadiene.

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