Abstract
Abstract The reaction of cis-Cp*(CO)2HW=SiPh2·Py (1, Py = pyridine) with HCl gave an adduct Cp*(CO)2H2WSiPh2Cl (2). Treatment of 2 with excess LiAlH4 afforded an anionic complex Li[cis-Cp*(CO)2HWSiHPh2] (4), and the same product was obtained by the reaction of 1 with LiAlH4.
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