Abstract
Depending on the reactant ratio and order of their mixing, reactions of dialkyl hydrogen phosphite with alkenes in the presence of catalytic amounts of homoligand carbonyl complexes of iron or chromium subgroup metals yield phosphonates by two pathways: reaction of dialkyl hydrogen phosphite with π-coordinated alkene and addition to alkene of the product of reaction of dialkyl hydrogen phosphite with the transition metal carbonyl. The products of reactions of Fe(CO)5 and W(CO)6 with dialkyl hydrogen phosphites contain the phosphorus-metal bond.
Full Text 
Sign-in/Register to access full text options
Sign-in/Register to access full text options 
Paper version not known
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
