Abstract
The free radical‐catalyzed bisulfite addition to octene‐1, decene‐1, dodecene‐1 and tetradecene‐1 was studied under different conditions. The experimental conditions could be adjusted to yield different ratios of intermediate as well as final compounds. We have separated, purified and positively identified alkane‐1‐sodium sulfonates of general formula CH3‐(CH2)n‐SO3Na (n=7,9,11 and 13), alkane‐1‐sodium sulfonate‐2‐sulfinic acids of general formula CH3‐(CH2)n‐CHSO2H‐CH2‐SO3Na (n=5,7,9 and 11) and alkane‐1,2‐disodium sulfonates of general formula CH3‐(CH2)n‐CHSO3Na‐CH2‐SO3Na (n=5,7,9 and 11).The solubilities and critical micelle concentrations of mono‐ and disodium alkane sulfonates were determined, and for definite identification13C nuclear magnetic resonance (NMR) and dispersive X‐ray crystallography were employed along with classical wet analytical procedures.
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