Abstract
A two-dimensional lattice-gas model with square symmetry is investigated by using the real-space renormalization group (RSRG) approach with blocks of different size and symmetries. It has been shown that the precision of the method depends strongly not only on the number of sites in the block but also on its symmetry. In general, the accuracy of the method increases with the number of sites in the block. The minimal relative error in determining the critical values of the interaction parameters is equal to \(\). Using the RSRG method, we have explored phase diagrams of both a two-dimensional Ising spin model and of a square lattice gas with lateral interactions between adparticles. We also have investigated the influence of the attractive and repulsive interactions on both the thermodynamic properties of the lattice gas and the diffusion of adsorbed particles over surface. We have calculated adsorption isotherms and coverage dependences of the pair correlation function, isothermal susceptibility and the chemical diffusion coefficient. In addition, we have included in our analysis the interaction of the activated particle in the saddle point with its nearest neighbors. We have also used Monte Carlo (MC) technique to calculate these dependences. Despite the fact that both methods constitute very different approaches, the correspondence of the numerical data is surprisingly good. Therefore, we conclude that the RSRG approach can be applied to characterize the thermodynamic and kinetic properties of systems of particles with strong lateral interactions.
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