Adaptive ferroelectric states in systems with low domain wall energy: Tetragonal microdomains

Abstract

Ferroelectric and ferroelastic phases with very low domain wall energies have been shown to form miniaturized microdomain structures. A theory of an adaptive ferroelectric phase has been developed to predict the microdomain-averaged crystal lattice parameters of this structurally inhomogeneous state. The theory is an extension of conventional martensite theory, applied to ferroelectric systems with very low domain wall energies. The case of ferroelectric microdomains of tetragonal symmetry is considered. It is shown for such a case that a nanoscale coherent mixture of microdomains can be interpreted as an adaptive ferroelectric phase, whose microdomain-averaged crystal lattice is monoclinic. The crystal lattice parameters of this monoclinic phase are self-adjusting parameters, which minimize the transformation stress. Self-adjustment is achieved by application of the invariant plane strain to the parent cubic lattice, and the value of the self-adjusted parameters is a linear superposition of the lattice constants of the parent and product phases. Experimental investigations of Pb(Mg1/3Nb2/3)O3–PbTiO3 and Pb(Zn1/3Nb2/3)O3–PbTiO3 single crystals confirm many of the predictions of this theory.