Abstract
With the continued interest in the properties of the difluoromethyl (CF2H) group, small molecules with alkyl-CF2H motifs have gained increasing attention. However, concise and efficient synthetic protocols to achieve these structures are still urgently needed. Herein, we report a new acyldifluoromethylation of inert alkenes via a synergistic NHC-photoredox catalysis featuring broad substrate scope and good functional group tolerance.
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