Abstract
Titanium(III) π-allylic complexes, prepared by the interaction of 1,3-dienes or trienes with Cp 2TiCl 2 and n-PrMgBr, react with carboxylic acid chlorides RCOCl (R = alkyl, aryl, alkenyl) to give β, γ-unsaturated ketones in high yields. The reaction takes place at the most substituted carbon atom of the π-allylic ligand.
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