Abstract

The phenylosazone acetates from pentoses, 6-deoxyhexoses and hexoses were boiled with acetic anhydride yielding dianhydrophenylosazone acetates of the type (Ia–c). Similarly, p-chlorophenylosazones from d-glucose, l-sorbose and d-arabinose yielded dianhydro- p-chlorophenylosazone acetates. Acetyl chloride reacted with the phenylosazones from d-glucose and d-galactose yielding the N-acetyl-tetra- O-acetyl derivatives (III) and (IV). The phenylosazones from d-glucose and l-sorbose gave a tetra- and a mono- O-benzoyl derivative, respectively, in crystalline form when an insufficient amount of benzoyl chloride was used during benzoylation.

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