Abstract

Layered zeolite precursor MCM-22P can be stabilized as interlayer expanded structure MWW-IEZ with enlarged pores by silylation producing –O–Si(OH)2–O– bridges. It adsorbs two times more cerium than MCM-22 and becomes activated for CO oxidation to CO2 at room temperature. This represents one of the most notable activity enhancements upon modification of layered zeolites.

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