Abstract
The activity coefficients at infinite dilution at various temperatures have been determined by g.l.c. for all the tetramethyl compounds of Group 14 elements in the solvents n-dodecane, n-hexadecane, n-eicosane, and n-tetracosane; the excess partial molar enthalpies at infinite dilution have been calculated. The activity coefficients have been discussed in terms of the quasi-lattice theory. The “segment” and “contact-point” treatments previously used for n-alkane mixtures and for (an n-alkane + benzene) have been extended to (an n-alkane + a tetramethyl compound).
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