Activation stainless steel with electrochemical etching-hydrothermal as an efficient and stable alkaline water oxidation electrode

Abstract

Stainless steel (SS) has great potential to become an efficient oxygen evolution reaction (OER) catalytic material, but an effective activation method is still lacking. Here, an electrochemical etching-hydrothermal activation strategy is proposed to turn SS into an efficient and stable OER electrode, which can deliver high current density of 300 mA cm−2 with only 314 mV, as well as offers a low Tafel slope of 30 mV dec−1. The catalytic phase formed by the activation has a low surface Ni/Fe ratio and completely disobeys the traditional “Fe-effect” activity trend. The performed O–K edge X-ray adsorption spectra revealed that the high valence states of Ni sites with modified electronic structure may be responsible for the enhanced OER performance. More importantly, the assembled overall water-splitting cell showed that it can withstand long-term durability of 100 h at an ultra-high current density of 2 A cm−2. The strategy presented here could yield an opportunity to convert SS into an efficient and robust catalyst for alkaline water oxidation and is expected to lead to more promising ones due to the diverse composition of SS.