Abstract

The reduction of [C5Me4(SiMe3)]2TiCl2 by excess Mg in THF yields the paramagnetic compound {[η5-C5Me4SiMe2(μ-CH2{Mg,Mg})][η5-C5Me4(SiMe3)]TiIII(μ-H)2Mg(THF)}2 (3). In the presence of Me3SiC⋮CSiMe3 ...

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