Abstract
Abstract The germane intermediate σ-complexes, characterized by high-field resonances in the region from −6 to −8 ppm, have been detected during the 1 H NMR spectroscopy monitoring of the photochemical reaction of Et 3 GeH with Mo(CO) 6 , [Mo(CO) 4 (η 4 -cod)], and [Mo(CO) 4 (η 4 -nbd)] in the NMR tube. The activation of the Ge–H bond of germane in photochemical reaction of the norbornadiene (nbd) complex [Mo(CO) 4 (η 4 -nbd)] has been applied in the hydrogermylation of norbornadiene, which leads to the formation of triethylgermylnorbornene.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
