Abstract
Rhodium hydrido chloride pincer complex RhH(Cl)[2,6-(Buptb2PO)b2Cb6Hb3] was synthesized and used for the preparation of new complexes with labile two-electron ligands Rh(L)[2,6-(Buptb2PO)b2Cb6Hb3] (L = MeCN or S(CHb2)b4) and complexes with small molecules, such as CO, Ob2, Hb2, and Nb2.
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