Activation of persulfate and removal of ethyl-parathion from soil: Effect of microwave irradiation

Abstract

Advanced persulfate oxidation technology is widely used in organic pollution control of super fund sites. In recent years, microwave radiation has been proven a promising method for persulfate activation. However, most of the prior works were focused on the treatment of polluted water, but there are few reports aiming at contaminated sites, especially the knowledge of using microwave activated persulfate technology to repair pesticide-contaminated sites. In this study, an effective activation/oxidation method for the remediation of pesticide-contaminated soil, i.e., microwave/persulfate, was developed to treat soil containing ethyl-parathion. The concentration of persulfate, reaction temperature, and time were optimised. The results showed that up to 77.32% of ethyl-parathion was removed with the addition of 0.1 mmol·persulfate·g−1 soil under the microwave temperature of 60 °C. In comparison, 19.43% of ethyl-parathion was removed at the same reaction temperature under the condition of water bath activated persulfate. Electron paramagnetic resonance (EPR) spectroscopy combined with spin-trapping technology was used to detect reactive oxidation species, and OH and SO4− were observed in the microwave/persulfate system. Quenching experiments suggested that ethyl-parathion was degraded by the generated OH and SO4−. Paraoxon, phenylphosphoric acid, 4-nitrophenol, dimethyl ester phosphate, and some alkanes were the dominant oxidative products identified by gas chromatography–mass spectrometry (GC-MS) analysis. A possible pathway for ethyl-parathion degradation was proposed in this study. The results obtained serve as the guidance to the development of remediation technologies involving persulfate and microwave for soil contaminated by organic contaminants such as pesticides.