Abstract
Results on catalytic activation and functionalisation of light alkanes by soluble metal complexes in homogeneous solutions are reviewed. Under discussion are H/D exchange, oxidation, carbonylation, and carboxylation of light alkanes catalyzed by a range of metal complex systems including Pt(II), Pt(IV), Pd(II), Rh(III), Hg(II), Ziegler-Natta catalysts, and polyoxometalates.
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