Abstract
The activation of CS2 by the 2H-phosphindole complex with a low-coordinate phosphadiene moiety is reported. The successive hetero-Diels-Alder reaction between 2H-phosphindoles and CS2 constructs two bridged rings and one spirocycle simultaneously, affording structurally complex P,S-polycyclic products. The two 2H-phosphindoles approach the C═S bond in a head-to-head disposition to minimize steric hindrance. This work reveals the unique reactivity of low-coordinate organophosphorus species and their potential applications in small molecule activation.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
