Activated g-C3N4 Photocatalyst with Defect Engineering for Efficient Reduction of CO2 in Water

Abstract

The conversion and utilization of CO2 into hydrocarbon fuel using solar energy is an attractive way to reduce CO2 emissions. In the photocatalytic CO2 conversion process, a synergistic enhancement of both photoreaction and chemical reaction is quite important for promoting the conversion. Here, we present a facile method for preparing a defective and activated graphitic carbon nitride (g-C3N4) photocatalyst, which exhibits a superior CO2-to-CO production of 32.06 μmol g–1 without sacrificial agent or noble metal. This is about 9.1 times higher than that of the defect containing g-C3N4 (3.51 μmol g–1). The activated g-C3N4, in which the TiO2 species coexist, not only improved the CO production to 54.03 umol g–1 but also reduced CO2 into CH4 with 2.50 umol g–1 in 5 h. This is because the coexistence of TiO2 species in activated g-C3N4 promotes molecule and electron transfer, as observed through experimental characterization techniques. Therefore, this work provides a novel insight into the synthesis of multifunctional g-C3N4 for efficient photocatalytic CO2 reduction with H2O.