Activated Carbon as an Adsorbent for CO2 Capture: Adsorption, Kinetics, and RSM Modeling.

Abstract

The main objective of this research is to investigate the adsorption isotherms and the optimization of the carbon dioxide (CO2) adsorption process on activated carbon (AC). The AC has been characterized by X-ray diffraction, scanning electron microscopy, and nitrogen (N2) adsorption-desorption. The CO2 isotherms measured under three adsorption temperatures (318, 308, and 298 K) were investigated by the Langmuir and linear driving force model. It is found that the Langmuir model could well predict the adsorption behavior of AC with a correlation factor of about 0.99. The kinetic model shows that the amount of CO2 increases at higher pressures. The response surface methodology (RSM) was applied to investigate the effects of process variables and their interaction on the response to reach the optimal conditions. Based on the analysis of variance, pressure and temperature are the main factors influencing the CO2 adsorption capacity. The effective parameters obtained through this model are found to have a value of p < 0.05. In addition, a semiempirical correlation was developed under the optimal operating conditions which are 25 °C and 9 bar. The results indicated that RSM models provide an effective method for evaluating CO2 adsorption. These results point that AC is a potential adsorbent for CO2 capture.