Abstract
Rhodium(I) carbonyl formato complex, trans-[Rh(HCOO)(PPh3)2(CO)], on heating in propanol-2 in the presence of excess triphenylphosphine converts into carbonyl hydride complex, [HRh(PPh3)3(CO)], with a good yield. The reaction provides a new and attractive method of synthesis of [HRh(PPh3)3(CO)].
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