Acquisition of mid-infrared spectra from nonrepeatable events with sub-100-micros temporal resolution using planar array infrared spectroscopy.

Abstract

A novel method is presented that is capable of collecting time-resolved vibrational spectroscopic information with sub-100-micros temporal resolution. Unlike previous step scan FT-IR approaches, the phenomena under study do not necessarily need to be repeatable. The methodology described herein is based on the planar array infrared (PA-IR) technique, which utilizes a spectrograph for wavelength dispersion and a mid-infrared focal plane array (FPA) detector for simultaneous detection of multiple wavelengths. Unlike previous PA-IR approaches, a rolling mode FPA is employed. This unique data readout mode, where data are read out of the array two rows at a time, is exploited to generate increased temporal resolution. The capabilities of this technique are demonstrated using the example of the electric field-induced Freedericksz transition of a nematic liquid crystal. It is shown that the orientational dynamics of a single transition can be tracked over a spectral range of 154 cm(-)(1) with a temporal resolution of 99.17 micros while requiring a total experimental time of less than 1 s.