Abstract

In this research, results of the investigation of the sliding friction and wear of yttria-stabilized tetragonal zirconia polycrystalline (Y-TZP) and Y-TZP-Al2O3 samples preliminarily subjected to low-temperature degradation are reported. The investigation was carried out using a pin-on-disk tribometer with simultaneous recording of acoustic emission (AE) and vibration acceleration. The sliding wear process was found to be determined by dynamic direct and inverse Y-TZP transformations detected by monoclinic and tetragonal X-ray diffraction peak ratios. The AE signals generated under direct and inverse transformations can be used to characterize wear and friction mechanisms as well as direct and inversed sliding-induced phase transformations. The AE signal energy grows with the friction coefficient and the inverse transformation degree. Reduction of the AE signal energy indicates establishing the mild wear stage caused by effective stress-induced direct martensitic transformation. The AE signal median frequency increases in the case of lower friction. Numerical studies of wear subsurface fracture under conditions of stress-induced martensitic transformation were used to elucidate the role played by the phase transformation in Y-TZP and Y-TZP-Al2O3. Martensitic transformation in Y-TZP was described with use of the non-associated dilatant plasticity model. Simulation results particularly show that increase in the value of dilatancy coefficient from 0 to 0.2 is accompanied by 25%−30% reduce in characteristic length and penetration depth of sliding-induced subsurface cracks. As shown the AE may be an effective tool for in-situ monitoring the subsurface wear of materials experiencing both direct and inverse transformations.

Highlights

  • Tetragonal zirconia polycrystalline ceramics (TZP) partially stabilized by 3 mol% of yttria (3Y-TZP) are a well-known material that makes it possible to combine high strength, fracture toughness, ion conductance, and low thermal conduction

  • The low-temperature degradation (LTD) may occur in the 20−400 °C range when polycrystalline 100% tetragonal-phase material slowly transforms into a monoclinic zirconia with corresponding fast degradation of strength and fracture toughness

  • Experimental time dependencies characterizing the friction coefficient, acoustic emission (AE) median frequency, AE signal energy, and root mean square (RMS) vibrational accelerations in two perpendicular planes are shown in Fig. 1, Fig. 2, Fig. 4, and Fig. 5 for different sliding-speed and normal-load values as obtained on LTD-aged yttria-stabilized tetragonal zirconia polycrystalline (Y-TZP)/steel and Y-TZP-Al2O3/steel couples

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Summary

Introduction

Tetragonal zirconia polycrystalline ceramics (TZP) partially stabilized by 3 mol% of yttria (3Y-TZP) are a well-known material that makes it possible to combine high strength, fracture toughness, ion conductance, and low thermal conduction. They have been evaluated for numerous applications, ranging from thermal barrier coatings to biomedical materials. The LTD may occur in the 20−400 °C range when polycrystalline 100% tetragonal-phase material slowly transforms into a monoclinic zirconia with corresponding fast degradation of strength and fracture toughness. Phase transformation in LTD starts locally and results. The LTD may be inhibited by introducing various hard particles, such as alumina, and results in a ceramic material composite [3]

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