Abstract

We deposited self-assembled films of a few monolayers of silica spheres from the water-based colloid on vertically moving hydrophilic single crystal diamond substrates. The use of acoustic agitation of the water suspension with the SiO2 nanospheres significantly improved the long-range order of the films with opal structure. The study examines the evolution of the structure, specifically the size of single crystal domains, with the assistance of sound frequency (0–2500 Hz) and intensity (0–125 dB). Optimal (resonance) parameters are determined based on scanning electron microscopy and optical reflection spectroscopy of the films. The production of high-quality photonic crystals, including templates for diamond-based ordered composites and inverse opal structures, is a promising application of acoustic crystallization of opals on diamond substrates.

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