Acid‐susceptive material as a host phase of argon‐rich noble gas in the carbonaceous chondrite Ningqiang

Abstract

Abstract— A fine‐grained dark inclusion in the Ningqiang carbonaceous chondrite consists of relatively pristine solar nebular materials and has high concentrations of heavy primordial rare gases. Trapped 36Ar concentration amounts to 6 times 10−6 cc STP/g, which is higher than that of Ningqiang host by a factor of three. Light HF‐HCl etching of the dark inclusion removed 86, 73, and 64% of the primordial 36Ar, 84Kr, and 132Xe, respectively. Thus, the majority of the noble gases in this inclusion are located in very acid‐susceptive material. Based on the elemental composition, the noble gases lost from the dark inclusion during the acid‐treatments are Ar‐rich, and the noble gases remaining in the inclusion are Q and HL gases. Transmission electron microscopy showed that the acid treatments removed thin Si, Mg, and Fe‐rich amorphous rims present around small olivine and pyroxene grains in the dark inclusion, suggesting that the Ar‐rich gases reside in the amorphous layers. A possible origin of the Ar‐rich gases is the acquisition of noble‐gas ions with a composition fractionated relative to solar abundance favoring the heavy elements by the effect of incomplete ionization under plasma conditions at 8000 K electron temperature.