Abstract
A detailed investigation of the rearrangement of the major taxane from Taxus canadensis enables to suggest the sequence of the reactions involved: 9-dihydro- 13-acetylbaccatin III → abeo-taxanes with intact oxetane and acyl migration → abeo-taxanes with intact oxetane and deacylation → abeo-taxanes with opening of the oxetane and various acyl migrations including two unusual benzoyl shifts.
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