Achiral copper clusters helically confined in self-assembled chiral nanotubes emitting circularly polarized phosphorescence

Abstract

Achiral Cu5− cluster coassembled with a chiral amphiphile to afford helical nanotubes, where the Cu5− cluster was confined within the nanotubes, forming helical arrangement with emerged chiroptical activities (CD and CPP), with a large gabs up to 0.018.