Achievements in Pt nanoalloy oxygen reduction reaction catalysts: strain engineering, stability and atom utilization efficiency.

Abstract

The Pt nanoalloy surfaces often show unique electronic and physicochemical properties that are distinct from those of their parent metals, which provide significant room for manipulating their oxygen reduction reaction (ORR) behaviour. In this Feature Article, we present the progress of our recent research and that of other groups in Pt nanoalloy catalysts for ORR from three aspects, namely, strain engineering, stability and atom utilization efficiency. Some new insights into Pt surface strain engineering will be firstly introduced, with a focus on discussing the effect of compressive and tensile strain on the chemisorption properties. Secondly, the design concepts and synthetic methodologies to intensify the inherent stability of Pt nanoalloys will be summarized. Then, the exciting research push in developing nanostructured alloys with high atom utilization efficiency of Pt will be presented. Finally, a brief illumination of challenges and future developing perspectives of Pt nanoalloy catalysts will be provided.