Abstract
The tridentate Schiff base ligand in the title compound, [V(C16H14N2O3)(CH3O)O], has its O, N and O′ atoms spanning three basal positions of the square-based-pyrimidally VV atom. The fourth basal site is occupied by a methoxo ligand, which results from a deprotonated methanol solvent molecule, and the oxido ligand occupies the apical position. The hydroxy H atom forms an intramolecular O—H⋯N hydrogen bond with an N-atom acceptor site.
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