Abstract
In the title compound, [Ir(C18H12NO2)2(C5H7O2)], the Ir atom is O,O′-chelated by the acetylacetonate group and C,N-chelated by the 2-arylnaphth[1,2-d]oxazole groups. The six-coordinate metal atom displays a distorted octahedral geometry. Intramolecular C—H⋯O hydrogen bonds occur. In the crystal, intermolecular C—H⋯O hydrogen bonds link the molecules into columns parallel to the b axis.
Highlights
In the title compound, [Ir(C18H12NO2)2(C5H7O2)], the Ir atom is O,O0 -chelated by the acetylacetonate group and C,Nchelated by the 2-arylnaphth[1,2-d]oxazole groups
Intermolecular C—H O hydrogen bonds link the molecules into columns parallel to the b axis
R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger
Summary
(Acetylacetonato-j2O,O0 )bis[5-methoxy2-(naphth[1,2-d][1,3]oxazol-2-yl)phenylj2C 1,N]iridium(III) Zhoud a Institute of Electric Power, North China University of Water Resources and Electric Power, 450011, Zhengzhou, People’s Republic of China, bDepartment of Environment Engineering and Chemistry, Luoyang Institute of Science and Technology, 471023, Luoyang, People’s Republic of China, cChemistry Department, Zhengzhou University, 450052, Zhengzhou, People’s Republic of China, and d
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