Abstract

In the crystal structure of the title compound, [Ir(C17H10NO)2(C5H7O2)], the IrIII atom is O,O′-chelated by the acetyl­acetonate group and C,N-chelated by the 2-aryl­naphth[1,2-d]oxazole groups. The six-coordinate metal atom displays a distorted octa­hedral geometry.

Highlights

  • In the crystal structure of the title compound, [Ir(C17H10NO)2(C5H7O2)], the IrIII atom is O,O0-chelated by the acetylacetonate group and C,N-chelated by the 2-arylnaphth[1,2-d]oxazole groups

  • Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: SI2371)

  • R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger

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Summary

Guojie Yin

Key indicators: single-crystal X-ray study; T = 273 K; mean (C–C) = 0.005 A; R factor = 0.023; wR factor = 0.051; data-to-parameter ratio = 18.2. Crystal data [Ir(C17H10NO)2(C5H7O2)] Mr = 779.83 Monoclinic, C2=c a = 16.640 (3) Ab = 17.384 (3) Ac = 21.461 (4) A = 95.026 (2)

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