Abstract
The acetonitrile ligand in the title compound, [W(CH3CN)(CO)5], is coordinated end-on to a pentacarbonyltungsten(0) fragment with a W—N bond length of 2.186 (4) Å, completing an octahedral coordination environment around the W atom.
Highlights
The acetonitrile ligand in the title compound, [W(CH3CN)(CO)5], is coordinated end-on to a pentacarbonyltungsten(0) fragment with a W—N bond length of 2.186 (4) A, completing an octahedral coordination environment around the W atom
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: DS2110)
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2)
Summary
Key indicators: single-crystal X-ray study; T = 100 K; mean (C–C) = 0.006 A; R factor = 0.022; wR factor = 0.055; data-to-parameter ratio = 15.4. The acetonitrile ligand in the title compound, [W(CH3CN)(CO)5], is coordinated end-on to a pentacarbonyltungsten(0) fragment with a W—N bond length of 2.186 (4) A , completing an octahedral coordination environment around the W atom. Related literature For other structures with an (alkyl nitrile-N)pentacarbonyltungsten(0) fragment, see: Darensbourg et al (1992); Reibenspies et al (1994); Jefford et al (1996). Crystal data [W(C2H3N)(CO)5] Mr = 364.95 Monoclinic, P21=n a = 5.6485 (6) Ab = 13.6231 (15) Ac = 12.8642 (15) A
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