Abstract
In the title cationic Cp*Fe(II) complex, [Fe(C10H15)(CH3CN)(C14H16NP)]PF6·C4H8O, the metal ion is coordinated by the η 5-Cp* ring as well as the P and N atoms of the chelating 2-(diphenylphosphino)ethylamine ligand and an additional acetonitrile molecule in a piano-chair conformation. The PF6 − anion is disordered over two sets of sites with occupancies of 0.779 (7) and 0.221 (7).
Highlights
Structure Reports OnlineKey indicators: single-crystal X-ray study; T = 200 K; mean (C–C) = 0.005 A; disorder in solvent or counterion; R factor = 0.045; wR factor = 0.115; data-toparameter ratio = 17.9
In the title cationic Cp*Fe(II) complex, [Fe(C10H15)(CH3CN)(C14H16NP)]PF6ÁC4H8O, the metal ion is coordinated by the 5-Cp* ring as well as the P and N atoms of the chelating 2(diphenylphosphino)ethylamine ligand and an additional acetonitrile molecule in a piano-chair conformation
The PF6À anion is disordered over two sets of sites with occupancies of 0.779 (7) and 0.221 (7)
Summary
Key indicators: single-crystal X-ray study; T = 200 K; mean (C–C) = 0.005 A; disorder in solvent or counterion; R factor = 0.045; wR factor = 0.115; data-toparameter ratio = 17.9. In the title cationic Cp*Fe(II) complex, [Fe(C10H15)(CH3CN)(C14H16NP)]PF6ÁC4H8O, the metal ion is coordinated by the 5-Cp* ring as well as the P and N atoms of the chelating 2(diphenylphosphino)ethylamine ligand and an additional acetonitrile molecule in a piano-chair conformation. The PF6À anion is disordered over two sets of sites with occupancies of 0.779 (7) and 0.221 (7). Related literature For related ruthenium complexes, see: Ito et al (2003, 2005, 2007, 2009, 2011). For corresponding Fe(II) complexes, see: Davies et al (1994); Lagaditis et al (2010). For the structure of a similar iron complex, see: Barbier et al (1979).
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