Abstract
In the title complex, [Ni(CH3COO)(C28H26N4)]ClO4, the NiII atom is coordinated by two imine N atoms and two pyridine N atoms of the N-[(E)-1-(6-methyl-2-pyridyl)methylidene]-2-(2-[(E)-1-(6-methyl-2-pyridyl)methylideneamino]phenethyl)aniline donor ligand and two O atoms of the acetate ion in a distorted octahedral coordination. The average Ni—N and Ni—O bond lengths are 2.131 (13) and 2.098 (11) Å, respectively. An intramolecular N—H⋯O interaction occurs. Relatively weak intermolecular C—H⋯O interactions between the ligands and the ClO4 − ions result in a chain extending along the b axis.
Highlights
In the title complex, [Ni(CH3COO)(C28H26N4)]ClO4, the NiII atom is coordinated by two imine N atoms and two pyridine N atoms of the N-[(E)-1-(6-methyl-2-pyridyl)methylidene]-2(2-[(E)-1-(6-methyl-2-pyridyl)methylideneamino]phenethyl)aniline donor ligand and two O atoms of the acetate ion in a distorted octahedral coordination
For structures of Ni complexes with ligands formed by the condensation of 2-pyridyl aldehydes and a variety of diamines, see: Banerjee et al (2004)
We report the synthesis and crystal structure of the title complex
Summary
Acetato(N-[(E)-1-(6-methyl-2-pyridyl)methylidene]-2-{2-[(E)-1-(6-methyl-2pyridyl)methylideneamino]phenethyl}aniline)nickel(II) perchlorate a b a Shuranjan Sarkar, Hajin Lee and Hong-In Lee *.
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