Abstract

We report calculation of reaction probabilities and branching ratios for the four-atom reaction HD + OH → H + DOH, D + OH 2 on the modified Schatz-Elgersma potential energy surface using the time-dependent approach developed previously for studying H 2 + OH reaction. The branching ratio P DOH P HOH is smaller than the one at low collision energies where hydrogen tunneling is dominant, but is greater than the one at high collision energies. The explanation for the isotope branching ratio is furnished.

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