Abstract
1-Phosphapropyne has been produced in the gas phase by pyrolysis of a mixture of ethane and phosphorus trichloride. The ground state rotational spectra of the most abundant isotopomer and of the isotopic variants 13 CH 3 CP and CH 3 13 CP have been investigated in the millimeter and submillimeter wave regions obtaining very accurate values of the quartic centrifugal distortion constants D J and D JK and of the sextic distortion constants H JK and H KJ .
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