Abstract

Aerosol water content plays an important role in aqueous phase reactions, in controlling visibility, and in cloud formation processes. One way to quantify aerosol water content is to measure hygroscopic growth using the hygroscopicity tandem differential mobility analyzer (HTDMA) technique. However, the HTDMA technique becomes less reliable at relative humidity (RH) >90% due to the difficulty of controlling temperature and RH inside the second DMA. For this study, we have designed and implemented a new HTDMA system with improved temperature and RH control. Temperature stability in the second DMA was achieved to ±0.02°C tolerance by implementing active control using thermoelectric heat exchangers and PID control loops. The DMA size resolution was increased by operating high-flow DMA columns at a sheath:sample flow ratio of 15:0.5. This improved size resolution allowed for improving the accuracy of the RH sensors by interspersing ammonium sulfate reference scans at high frequency. We present growth factor d...

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.