Abstract

The accumulation of Au(0) by lyophilized preparations of the alga Chlorella vulgaris has been investigated. Gold is bound to the algae upon suspending dried algal cells in solutions containing hydrogen tetrachloroaurate (III). Relative amounts of ionic and atomic algal-bound gold were determined by thiourea extraction. It was found that the amount of algal-bound atomic gold produced from ionic gold increased with time. The effect of algal-bound gold concentration on the rate and extent of gold reduction was observed. It is suggested that at least three different classes of sites are available for gold binding and reduction. The effect of Au(0) accumulation on the binding ability of gold-bound algae was also investigated, and an apparent enhancement of gold binding ability is reported.

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