Accumulating characteristics of platinum group elements (PGE) in urban environments, China

Abstract

The three-way catalytic converters [mainly using platinum, palladium and rhodium of platinum group elements (PGE)] have been widely used to reduce the pollution arising from vehicular traffic. Since the late 1990s, the Chinese government has implemented measures for new vehicles, equipped with the three-way catalytic converters in metropolitan cities. However, the PGE spreading on environments has not been strongly concerned in developing countries. This study investigated the accumulation characteristics of PGE in urban environments in China. A few samples from India were also analyzed and compared with those from China. The collected soil, aerosol and plant samples were determined for PGE by inductively coupled plasma–mass spectrometry (ICP-MS) after nickel sulphide fire assay preconcentration. The results have shown higher PGE contents in the samples from the cities where vehicles were fitted with autocatalysts for longer time periods. The highest values are 160 ng/g for Pt, 107 ng/g for Pd and 34.5 ng/g for Rh in Hong Kong soils, whereas the lowest values are 2.59 ng/g for Pt, 1.31 ng/g for Pd and 0.40 ng/g for Rh in Kolkata soils. In Beijing and Guangzhou aerosol samples, the PGE concentrations are 6.22 to 24.3 pg/m 3 for Pt and 1.16 to 8.60 pg/m 3 for Rh and 7.68 to 12.2 pg/m 3 for Pt and 2.15 to 5.15 pg/m 3 for Rh, respectively. The levels of PGE abundances in the urban environments of China have been significantly elevated with increasing number of vehicles equipped with autocatalysts.